Alicyclics and Aromatics:
1. Carbon Chains can form two types of closed loops
2. Alicyclics are loops usually made with single bonds
3. If the parent chain is a loop standard naming rules apply with one addition:
"cyclo" is added in front of the parent chain
Cyclopeptane:
1. There are three different ways to draw organic compounds
complete structural diagrams:
condensed structural diagrams:
2. Numbering can start anywhere and go C.W. or C.C.W on the loop but side chains need
the lowest numbers possible
ex: trimethyl hexane :
3. Loops can be a side chain
4. Same rules apply but the side chain is given a cyclo-prefix
ex: cyclobutyl octane
Aromatics:
1. Benzene [ C6H6 ] is a cyclic hydrocarbon with unique bonds between the carbon atoms
2. Structurally it can be drawn with alternating double bonds
3. Careful analysis shows that all 6 C-C bonds are identical and really represent
a 1.5 bond
4. This is due to e- resonance
5. E- are free to move all around the ring
Aromatic Nonmenclature:
1. A benzene molecule is given a special diagram to show its unique bond structure
2. Benzene can be a parent chain or side chain "phenyl"
ex: pentamethyl benzene
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